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1)
Out of the following pair, which one does not have identical dimensions is
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1 )  
moment of inertia and moment of a force
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2 )  
work and torque
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3 )  
angular momentum and Planck's constant
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4 )  
impulse and momentum
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| see the answer see the solution |
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2)
The relation between time t and distance x is t = ax2 + bx where a and b are constants. The
acceleration is
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1 )  
2 av3
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2 )  
2 av2
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3 )  
- 2 abv2
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4 )  
2 bv3
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| see the answer see the solution |
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3)
A car starting from rest, accelerates at the rate f through a distance S, then continues at constant
speed for time t and then decelerates at the rate f/2 to come to rest. If the total distance traversed
is 15 S, then
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1 )  
S = (1/2) f t2
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2 )  
S = (1/72) f t2
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3 )  
S = (1/4) f t
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4 )  
S = (1/6) f t2
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| see the answer see the solution |
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4)
A particle is moving eastwards with a velocity of 5 ms-1. In 10 seconds the velocity changes to
5 ms-1 northwards. The average acceleration in this time is
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1 )  
zero
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2 )  
(1/ )ms-2 towards north-west
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3 )  
(1/ )ms-2 towards north-east
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4 )  
(1/2)ms-2 towards north
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5)
A projectile can have the same range R for two angles of projection. If t1 and t2 be the times of
flights in the two cases, then the product of the two time of flights is proportional to
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1 )  
1/R
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2 )  
R
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3 )  
R2
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4 )  
1/R2
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6)
An angular ring with inner and outer radii R1 and R2 is rolling without slipping with a uniform angular
speed. The ratio of the forces experienced by the two particles situated on the inner and outer parts
of the ring, F1 / F2 is
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1 )  
1
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2 )  
R1 / R2
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3 )  
R2 / R1
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4 )  
(R1 / R2)2
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7)
A smooth block is released at rest on a 45° incline and then slides a distance d. The time taken to
slide is n times as much to slide on rough incline than on a smooth incline. The coefficient of friction
is
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1 )  
μs = 1 - 1/n2
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2 )  
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3 )  
μk = 1 - 1/n2
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4 )  
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8)
The upper half of an inclined plane with inclination Φ is perfectly smooth while the lower half is rough.
A body starting from rest at the top will again come to rest at the bottom if the coefficient of friction
for the lower half is given by
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1 )  
2 tan Φ
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2 )  
tan Φ
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3 )  
2 sin Φ
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4 )  
2 cos Φ
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9)
A bullet fired into a fixed target loses half of its velocity after penetrating 3 cm. How much further it
will penetrate before coming to rest assuming that it faces constant resistance to motion?
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1 )  
1.5 cm
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2 )  
1.0 cm
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3 )  
3.0 cm
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4 )  
2.0 cm
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10)
A parachutist after bailing out falls 50 m without friction. When parachute opens, it decelerates at
2 m/s2. he reaches the ground with a speed of 3 m/s. At what height, did he bail out?
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1 )  
293 m
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2 )  
111 m
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3 )  
91 m
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4 )  
182 m
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11)
A particle of mass 0.3 kg is subjected to a force F = -kx with k = 15 N/m. What will be its initial
acceleration if it is released from a point 20 cm away from the origin?
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1 )  
5 m/s2
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2 )  
10 m/s2
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3 )  
3 m/s2
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4 )  
15 m/s2
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12)
The block of mass M moving on the frictionless horizontal surface collides with the spring of spring
constant K and compresses it by length L. The maximum momentum of the block after collision is

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1 )  
zero
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2 )  
ML2/K
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3 )  
L
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4 )  
( KL2 ) / ( 2M )
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13)
A mass m moves with a velocity v and collides inelastically with another identical mass. After collision
the 1st mass moves with velocity v/
in a direction perpendicular to the initial direction of motion.
Find the speed of the 2nd mass after collision
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1 )  
2 V /
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2 )  
V /
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3 )  
V
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4 )  
V
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| see the answer see the solution |
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14)
A spherical ball of mass 20 kg is stationary at the top of a hill of height 100 m. It rolls down a smooth
surface to the ground, then climbs up another hill of height 30 m and finally rolls down to a horizontal
base at a height of 20 m above the ground. The velocity attained by the ball is
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1 )  
10 m/s
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2 )  
10 m/s
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3 )  
40 m/s
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4 )  
20 m/s
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| see the answer see the solution |
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15)
A block is kept on a frictionless inclined surface with angle of inclination
α. The incline is given an acceleration a to keep the block stationary.
Then a is equal to

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1 )  
g
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2 )  
g tan α
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3 )  
g / tan α
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4 )  
g cosec α
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| see the answer see the solution |
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16)
The moment of inertia of a uniform semicircular disc of mass M and radius r about a lime perpendicular
to the plane of the disc through the centre is
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1 )  
Mr2
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2 )  
(1/2)Mr2
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3 )  
(1/4)Mr2
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4 )  
(2/5)Mr2
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| see the answer see the solution |
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17)
A body A of mass M while falling vertically downwards under gravity breaks into two parts: a body
B of mass 1/3 M and a body C of mass 2/3 M. The centre of mass of bodies B and C taken together
shifts compared to that of body A towards
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1 )  
body C
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2 )  
body B
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3 )  
depends on height of breaking
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4 )  
does not shift
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18)
A T shaped object with dimensions shown in the figure, is lying on a
smooth floor. A force F is applied at the point P parallel to AB, such
that the object has only the translational motion without rotation. Find
the location of P with respect to C.

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1 )  
(4/3) L
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2 )  
L
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3 )  
(2/3)L
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4 )  
(3/2)L
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| see the answer see the solution |
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19)
The change in the value of g at a height h above the surface of the earth is the same as at a depth d
below the surface of earth. When both d and h are much smaller than the radius of earth, then which
one of the following is correct?
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1 )  
d = 2h
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2 )  
d = h
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3 )  
d = h / 2
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4 )  
d = 3 h / 2
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20)
A particle of mass 10 g is kept on the surface of a uniform sphere of mass 100 kg and radius 10 cm.
Find the work to be done against the gravitational force between them to take the particle far away
from the sphere (you may take G = 6.67 x 10-11 Nm2/kg2)
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1 )  
6.67 x 10-9 J
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2 )  
6.67 x 10-10 J
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3 )  
13.34 x 10-10 J
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4 )  
3.33 x 10-10 J
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| see the answer see the solution |
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21)
A 20 cm long capillary tube is dipped in water. The water rises up to 8 cm. If the entire arrangement
is put in a freely falling elevator the length of water column in the capillary tube will be
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1 )  
4 cm
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2 )  
20 cm
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3 )  
8 cm
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4 )  
10 cm
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| see the answer see the solution |
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22)
If S is stress and Y is Young's modulus of material of a wire, the energy stored in the wire per unit
volume is
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1 )  
2 Y / S2
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2 )  
S / (2Y)
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3 )  
2 S2 Y
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4 )  
S2 / (2Y)
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| see the answer see the solution |
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23)
Average density of the earth
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1 )  
is directly proportional to g
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2 )  
is inversely proportionally to g
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3 )  
does not depend on g
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4 )  
is a complex function of g
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| see the answer see the solution |
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24)
A body of mass m is accelerated uniform from rest to a speed v in a time T. The instantaneous
power delivered to the body as a function of time is given by
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1 )  
(1/2) . (mv2/T2) . t
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2 )  
(1/2) . (mv2/T2) . t2
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3 )  
(mv2/T2) . t
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4 )  
(mv2/T2) . t2
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| see the answer see the solution |
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25)
Consider a car moving on a straight road with a speed of 100 m/s. The distance at which car can be
stopped is [μk = 0.5]
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1 )  
100 m
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2 )  
400 m
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3 )  
800 m
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4 )  
1000 m
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| see the answer see the solution |
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26)
Which of the following is incorrect regarding the first law of thermodynamics?
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1 )  
It introduces the concept of the internal energy
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2 )  
It introduces the concept of the entropy
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3 )  
It is not applicable to any cyclic process
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4 )  
It is a restatement of the principle of conservation of energy
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27)
The temperature-entropy diagram of a reversible engine
cycle is given in the figure. Its efficiency is
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1 )  
1 / 3
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2 )  
2 / 3
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3 )  
1 / 2
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4 )  
1 / 4
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28)
The figure shows a system of two concentric spheres of radii r1 and r2 and kept at temperature T1
and T2 respectively. The radial rate of flow of heat in a substance between the two concentric spheres
is proportional to
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1 )  
r1 r2 / ( r2 - r1 )
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2 )  
( r2 - r1 )
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3 )  
( r2 - r1 ) / ( r1 r2 )
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4 )  
ln (r2 / r1)
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29)
A system goes from A to B via two processes I and II as shown in figure. If ΔU1 and ΔU2
are the changes in internal energies in the process I and II respectively, then
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1 )  
ΔU2 > ΔU2
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2 )  
ΔU2 < ΔU2
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3 )  
ΔU2 = ΔU2
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4 )  
relation between ΔU1 and ΔU2 can not be determined
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30)
A gaseous mixture consists of 16 g of helium and 16 g of oxygen. The ratio
Cp / Cv of the mixture is
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1 )  
1.4
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2 )  
1.54
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3 )  
1.59
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4 )  
1.62
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| see the answer see the solution |
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31)
The intensity of gamma radiation from a given source is I. On passing through 36 mm of lead, it is
reduced to I / 8 . . The thickness of lead which will reduce the intensity to I / 2 will be
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1 )  
18 mm
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2 )  
12 mm
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3 )  
6 mm
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4 )  
9 mm
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| see the answer see the solution |
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32)
The electrical conductivity of a semiconductor increases when electromagnetic radiation of wavelength
shorter than 2480 nm is incident on it. The band gap in (eV) for the semiconductor is
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1 )  
0.5 eV
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2 )  
0.7 eV
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3 )  
1.1 eV
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4 )  
2.5 eV
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33)
A photocell is illuminated by a small bright source placed 1 m away. When the same source of light
is placed 1/2 m away, the number of electrons emitted by photocathode would
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1 )  
decrease by a factor of 2
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2 )  
increase by a factor of 2
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3 )  
decrease by a factor of 4
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4 )  
increase by a factor of 4
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| see the answer see the solution |
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34)
Starting with a sample of pure 66Cu, 7/8 of it decays into Zn in 15 minutes. The corresponding halflife is
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1 )  
5 minutes
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2 )  
71/2 minutes
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3 )  
10 minutes
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4 )  
15 minutes
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| see the answer see the solution |
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35)
If radius of the
nucleus is estimated to be 3.6 Fermi then the radius of nucleus be nearly
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1 )  
4 fermi
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2 )  
5 fermi
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3 )  
6 fermi
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4 )  
8 fermi
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36)
The diagram shows the energy levels for an electron in a
certain atom. Which transition shown represents the
emission of a photon with the most energy?
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1 )  
I
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2 )  
II
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3 )  
III
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4 )  
IV
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| see the answer see the solution |
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37)
If the kinetic energy of a free electron doubles, its deBroglie wavelength changes by the factor
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1 )  
1/
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2 )  
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3 )  
1/2
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4 )  
2
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| see the answer see the solution |
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38)
In a common base amplifier, the phase difference between the input signal voltage and output voltage is
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1 )  
0
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2 )  
π/2
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3 )  
π/4
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4 )  
π
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| see the answer see the solution |
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39)
In a full wave rectifier circuit operating from 50 Hz mains frequency, the fundamental frequency in
the ripple would be
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1 )  
100 Hz
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2 )  
70.7 Hz
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3 )  
50 Hz
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4 )  
25 Hz
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| see the answer see the solution |
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40)
A nuclear transformation is denoted by X(n, α)
. Which of the following is the nucleus of element X?
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1 )  
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2 )  
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3 )  
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4 )  
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| see the answer see the solution |
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41)
The function sin2(ωt) represents
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1 )  
a simple harmonic motion with a period 2p/ω
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2 )  
a simple harmonic motion with a period p/ω
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3 )  
a periodic, but not simple harmonic motion with a period 2p/ω
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4 )  
a periodic, but not simple harmonic motion with a period p/ω
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| see the answer see the solution |
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42)
A Young's double slit experiment uses a monochromatic source. The shape of the interference fringes
formed on a screen is
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1 )  
straight line
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2 )  
parabola
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3 )  
hyperbola
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4 )  
circle
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| see the answer see the solution |
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43)
Two simple harmonic motions are represented by the equation
y1 = 0.1 sin ( 100 πt + π/3 ) and y2 = 0.1 cos πt .
The phase difference of the velocity of particle 1 with respect to the velocity of
particle 2 is
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1 )  
- π/3
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2 )  
π/6
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3 )  
- π/6
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4 )  
π/3
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| see the answer see the solution |
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44)
A fish looking up through the water sees the outside world contained in a circular horizon. If the
refractive index of water is 4/3 and the fish is 12 cm below the surface, the radius of this
circle in cm is
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1 )  
36
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2 )  
4
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3 )  
36
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4 )  
36/
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| see the answer see the solution |
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45)
Two point white dots are 1 mm apart on a black paper. They are viewed by eye of pupil diameter
3 mm. Approximately, what is the maximum distance at which these dots can be resolved by the
eye? [Take wavelength of light = 500 nm]
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1 )  
6 m
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2 )  
3 m
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3 )  
5 m
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4 )  
1 m
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| see the answer see the solution |
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46)
A thin glass (refractive index 1.5) lens has optical power of 5 D in air. Its optical power in a liquid
medium with refractive index 1.6 will be
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1 )  
25 D
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2 )  
-25 D
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3 )  
1 D
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4 )  
-1 D
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| see the answer see the solution |
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47)
When two tuning forks (fork 1 and fork 2) are sounded simultaneously, 4 beats per second are head.
Now, some tape is attached on the prong of the fork 2. When the tuning forks are sounded again, 6
beats per second are heard. If the frequency of fork 1 is 200 Hz, then what was the original frequency
of fork 2?
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1 )  
196 Hz
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2 )  
204 Hz
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3 )  
200 Hz
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4 )  
202 Hz
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| see the answer see the solution |
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48)
If a simple harmonic motion is represented by d2x/dt2 + αx = 0 , its time period is
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1 )  
2πα
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2 )  
2π
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3 )  
2π/α
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4 )  
2π/
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| see the answer see the solution |
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49)
The bob of a simple pendulum is a spherical hollow ball filled with water. A plugged hole near the
bottom of the oscillating bob gets suddenly unplugged. During observation, till water is coming out,
the time period of oscillation would
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1 )  
remain unchanged
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2 )  
increase towards a saturation value
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3 )  
first increase and then decrease to the original value
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4 )  
first decrease and then increase to the original value
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| see the answer see the solution |
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50)
An observer moves towards a stationary source of sound, with a velocity one-fifth of the velocity of
sound. What is the percentage increase in the apparent frequency?
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1 )  
5 %
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2 )  
20 %
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3 )  
zero
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4 )  
0.5 %
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| see the answer see the solution |
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51)
If I0 is the intensity of the principal maximum in the single slit diffraction pattern,
then what will be its intensity when the slit width is doubled?
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1 )  
I0
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2 )  
I0/2
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3 )  
2 I0
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4 )  
4 I0
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| see the answer see the solution |
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52)
When an unpolarized light of intensity I0 is incident on a polarizing sheet, the intensity of the light
which does not get transmitted is
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1 )  
zero
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2 )  
I0
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3 )  
(1/2) I0
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4 )  
(1/4) I0
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| see the answer see the solution |
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53)
A charged ball B hangs from a silk thread S, which makes an angle θ
with a large charged conducting sheet P, as shown in the figure. The
surface charge density σ of the sheet is proportional to
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1 )  
sin θ
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2 )  
tan θ
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3 )  
cos θ
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4 )  
cot θ
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| see the answer see the solution |
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54)
Two point charges +8q and -2q are located at x = 0 and x = L respectively. The location of a point
on the x-axis at which the net electric field due to these two point charges is zero is
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1 )  
8 L
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2 )  
4 L
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3 )  
2 L
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4 )  
L / 2
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| see the answer see the solution |
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55)
Two thin rings each having a radius R are placed at a distance d apart with their axes coinciding.
The charges on the two rings are +q and -q. The potential difference between the centres of the
two rings is
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1 )  
zero
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2 )  
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3 )  
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4 )  
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| see the answer see the solution |
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56)
A parallel plate capacitor is made by stacking n equally spaced plates connected alternatively. If the
capacitance between any two adjacent plates is C then the resultant capacitance is
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1 )  
C
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2 )  
nC
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3 )  
(n - 1)C
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4 )  
(n + 1)C
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| see the answer see the solution |
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57)
A fully charged capacitor has a capacitance C. It is discharged through a small coil of resistance
wire embedded in a thermally insulated block of specific heat capacity s and mass m. If the temperature
of the block is raised by ΔT, the potential difference V across the capacitance is
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1 )  
msΔT/C
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2 )  
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3 )  
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4 )  
mCΔT/s
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| see the answer see the solution |
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58)
One conducting U tube can slide inside another as shown in figure, maintaining electrical contacts
between the tubes. The magnetic field B is perpendicular to the plane of the figure. If each tube
moves towards the other at a constant speed V, then the emf induced in the circuit in terms of B, l
and V where l is the width of each tube, will be

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1 )  
zero
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2 )  
2BlV
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3 )  
BlV
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4 )  
- BlV
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| see the answer see the solution |
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59)
A heater coil is cut into two equal parts and only one part is now used in the heater. The heat generated
will now be
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1 )  
one fourth
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2 )  
halved
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3 )  
doubled
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4 )  
four times
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| see the answer see the solution |
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60)
Two thin, long, parallel wires, separated by a distance d carry a current of i A in the same direction.
They will
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1 )  
attract each other with a force of μ0i2/(2πd2)
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2 )  
repel each other with a force of μ0i2/(2πd2)
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3 )  
attract each other with a force of μ0i2/(2πd )
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4 )  
repel each other with a force of μ0i2/(2πd )
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| see the answer see the solution |
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61)
A moving coil galvanometer has 150 equal divisions. Its current sensitivity is 10 divisions per milliampere
and voltage sensitivity is 2 divisions per millivolt. In order that each division reads 1 volt, the resistance
in ohms needed to be connected in series with the coil will be
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1 )  
99995
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2 )  
9995
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3 )  
103
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4 )  
105
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| see the answer see the solution |
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62)
Two voltameters, one of copper and another of silver, are joined in parallel. When a total charge q
flows through the voltammeters, equal amount of metals are deposited. If the electrochemical
equivalents of copper and silver are z1 and z2 respectively the charge which flows through the silver
voltameter is
|
|
|
1 )  
q . (z1/z2)
|
|
2 )  
q . (z2/z1)
|
|
3 )  
( q )/(1 + (z1/z2) )
|
|
4 )  
( q )/(1 + (z2/z1) )
|
| see the answer see the solution |
|
63)
In the circuit, the galvanometer G shows zero deflection.
If the batteries A and B have negligible internal resistance,
the value of the resistor R will be

|
|
|
1 )  
500 Ω
|
|
2 )  
1000 Ω
|
|
3 )  
200 Ω
|
|
4 )  
100 Ω
|
| see the answer see the solution |
|
64)
Two sources of equal emf are connected to an external resistance R. The internal resistances of the
two sources are R1 and R2 (R2 > R1).
If the potential difference across the source having internal
resistance R2 is zero, then
|
|
|
1 )  
R = (R1 . R2) / (R1 + R2)
|
|
2 )  
R = (R1 . R2) / (R2 - R1)
|
|
3 )  
R = R2 . ( (R1 + R2)/(R2 - R1) )
|
|
4 )  
R = R2 - R1
|
| see the answer see the solution |
|
65)
Two concentric coils each of radius equal to 2π cm are placed at right angles to each other. 3 ampere
and 4 ampere are the currents flowing in each coil respectively. The magnetic induction in Weber/m2
at the centre of the coils will be (μ0 = 4π x 10-7 Wb/Am)
|
|
|
1 )  
5 x 10-5
|
|
2 )  
7 x 10-5
|
|
3 )  
12 x 10-5
|
|
4 )  
10-5
|
| see the answer see the solution |
|
66)
A charged particle of mass m and charge q travels on a circular path of radius r that is perpendicular
to a magnetic field B. The time taken by the particle to complete one revolution is
|
|
|
1 )  
2πqB / m
|
|
2 )  
2πm / (qB)
|
|
3 )  
2πmq / B
|
|
4 )  
2πq2B / m
|
| see the answer see the solution |
|
67)
In a potentiometer experiment the balancing with a cell is at length 240 cm. On shunting the cell with
a resistance of 2 Ω , the balancing length becomes 120 cm. The internal resistance of the cell is
|
|
|
1 )  
4 Ω
|
|
2 )  
2 Ω
|
|
3 )  
1 Ω
|
|
4 )  
0.5 Ω
|
| see the answer see the solution |
|
68)
The resistance of hot tungsten filament is about 10 times the cold resistance. What will be the resistance
of 100 W and 200 V lamp when not in use?
|
|
|
1 )  
400 Ω
|
|
2 )  
200 Ω
|
|
3 )  
40 Ω
|
|
4 )  
20 Ω
|
| see the answer see the solution |
|
69)
A magnetic needle is kept in a non-uniform magnetic field. It experiences
|
|
|
1 )  
a force and a torque
|
|
2 )  
a force but not a torque
|
|
3 )  
a torque but not a force
|
|
4 )  
neither a force nor a torque
|
| see the answer see the solution |
|
70)
A uniform electric field and a uniform magnetic field are acting the same direction in a certain region.
If an electron is projected along the direction of the fields with a certain velocity then
|
|
|
1 )  
it will turn towards right of direction of motion
|
|
2 )  
it will turn towards left of direction of motion
|
|
3 )  
its velocity will decrease
|
|
4 )  
its velocity will increase
|
| see the answer see the solution |
|
71)
A coil of inductance 300 mH and resistance 2 Ω is connected to a sources of voltage 2 V. The
current reaches half of its steady state value in
|
|
|
1 )  
0.15 s
|
|
2 )  
0.3 s
|
|
3 )  
0.05 s
|
|
4 )  
0.1 s
|
| see the answer see the solution |
|
72)
The self inductance of the motor of an electric fan is 10 H. In order to impart maximum
power at 50 Hz, it should be connected to a capacitance of
|
|
|
1 )  
1 μF
|
|
2 )  
2 μF
|
|
3 )  
4 μF
|
|
4 )  
8 μF
|
| see the answer see the solution |
|
73)
An energy source will supply a constant current into the load if its internal resistance is
|
|
|
1 )  
zero
|
|
2 )  
non-zero but less than the resistance of the load
|
|
3 )  
equal to the resistance of the load
|
|
4 )  
very large as compared to the load resistance
|
| see the answer see the solution |
|
74)
A circuit has a resistance of 12 ohm and an impedance of 15 ohm. The power factor of the circuit
will be
|
|
|
1 )  
1.25
|
|
2 )  
0.125
|
|
3 )  
0.8
|
|
4 )  
0.4
|
| see the answer see the solution |
|
75)
The phase difference between the alternating current and emf is π/2 . Which of the following cannot
be the constituent of the circuit?
|
|
|
1 )  
L, C
|
|
2 )  
L along
|
|
3 )  
C alone
|
|
4 )  
R, L
|
| see the answer see the solution |
|
76)
Which of the following oxides is amphoteric in amphoteric in character ?
|
|
|
1 )  
CaO
|
|
2 )  
CO2
|
|
3 )  
SiO2
|
|
4 )  
SnO2
|
| see the answer see the solution |
|
77)
Which one of the following species is diamagnetic in nature ?
|
|
|
1 )  
He2+
|
|
2 )  
H2
|
|
3 )  
H2+
|
|
4 )  
H2-
|
| see the answer see the solution |
|
78)
If α is the degree of dissociation of Na2SO4 the vant Hoff's factor (i) used for calculating the molecular
mass is
|
|
|
1 )  
1 + α
|
|
2 )  
1 - α
|
|
3 )  
1 + 2α
|
|
4 )  
1 - 2α
|
| see the answer see the solution |
|
79)
The oxidation state of Cr in [Cr(NH3)4Cl2]+ is
|
|
|
1 )  
+ 3
|
|
2 )  
+ 2
|
|
3 )  
+ 1
|
|
4 )  
0
|
| see the answer see the solution |
|
80)
Hydrogen bomb is based on the principle of
|
|
|
1 )  
nuclear fission
|
|
2 )  
natural radioactivity
|
|
3 )  
nuclear fusion
|
|
4 )  
artificial radioactivity
|
| see the answer see the solution |
|
81)
An ionic compound has a unit cell consisting of A ions at the corners of a cube and B ions on the
centres of the faces of the cube. The empirical formula for this compound would be
|
|
|
1 )  
AB
|
|
2 )  
A2B
|
|
3 )  
AB3
|
|
4 )  
A3B
|
| see the answer see the solution |
|
82)
For a spontaneous reaction, the ΔG, equilibrium constant (K) and E°cell
will be respectively
|
|
|
1 )  
-ve, > 1, +ve
|
|
2 )  
+ve, > 1, -ve
|
|
3 )  
-ve, <1, -ve
|
|
4 )  
-ve, >1, -ve
|
| see the answer see the solution |
|
83)
Which of the following is a polyamide?
|
|
|
1 )  
Teflon
|
|
2 )  
Nylon-66
|
|
3 )  
Terylene
|
|
4 )  
Bakelite
|
| see the answer see the solution |
|
84)
Which one of the following types of drugs reduces fever ?
|
|
|
1 )  
Analgesic
|
|
2 )  
Antipyretic
|
|
3 )  
Antibiotic
|
|
4 )  
Tranquiliser
|
| see the answer see the solution |
|
85)
Due to the presence of an unpaired electron, free radicals are :
|
|
|
1 )  
Chemically reactive
|
|
2 )  
Chemicaly inactive
|
|
3 )  
Anions
|
|
4 )  
Cations
|
| see the answer see the solution |
|
86)
Lattice energy of an ionic compound depends upon
|
|
|
1 )  
Charge on the ion only
|
|
2 )  
Size of the ion only
|
|
3 )  
Packing of ions only
|
|
4 )  
Charge on the ion and size of the ion
|
| see the answer see the solution |
|
87)
The highest electrical conductivity of the following aqueous solutions is of
|
|
|
1 )  
0.1 M acetic acid
|
|
2 )  
0.1 M chloroacetic acid
|
|
3 )  
0.1 M fluoroacetic acid
|
|
4 )  
0.1 M difluoroacetic acid
|
| see the answer see the solution |
|
88)
Aluminium oxide may be electolysed at 1000°C to furnish aluminium metal (at. mass = 27 amu;
1 Faraday = 96,500 Coulombs). The cathode reaction is
Al3+ + 3e- → Al°
To prepare 5.12 kg of aluminium metal by this method would require
|
|
|
1 )  
5.49 x 107 C of electricity
|
|
2 )  
1.83 x 107 C of electricity
|
|
3 )  
5.49 x 104 C of electricity
|
|
4 )  
5.49 x 101 C of electricity
|
| see the answer see the solution |
|
89)
Consider an endothermic reaction X→Y with the activation energies Eb and Ef for the backward and
forward reactions, respectively. In general
|
|
|
1 )  
Eb < Ef
|
|
2 )  
Eb > Ef
|
|
3 )  
Eb = Ef
|
|
4 )  
there is no definite relation between Eb and Ef
|
| see the answer see the solution |
|
90)
Consider the reaciton : N2 + 3H2 → 2NH3 carried out at
constant temperature and pressure. If ΔH and
ΔU are the enthalpy and internal energy changes for the reaction, which of the following expressions is
true ?
|
|
|
1 )  
ΔH = 0
|
|
2 )  
ΔH = ΔU
|
|
3 )  
ΔH < ΔU
|
|
4 )  
ΔH > ΔU
|
| see the answer see the solution |
|
91)
Which one of the following statements is NOT true about the effect of an increase in temperature on
the distribution of molecular speeds in a gas ?
|
|
|
1 )  
The most probable speed increases
|
|
2 )  
The fraction of the molecules with the most probable speed increases
|
|
3 )  
The distribution becomes broader
|
|
4 )  
The area under the distribution curve remains the same as under the lower temperature
|
| see the answer see the solution |
|
92)
The volume of a colloidal particel, Vc as compared to the volume of a
solute particle in a true solution Vs, could be
|
|
|
1 )  
Vc / Vs ≈ 1
|
|
2 )  
Vc / Vs ≈ 1023
|
|
3 )  
Vc / Vs ≈ 10-3
|
|
4 )  
Vc / Vs ≈ 103
|
| see the answer see the solution |
|
93)
The solubility product of a salt having general formula MX2, in water is : 4 x 10-12.
The concentration
of M2+ ions in the aqueous solution of the salt is
|
|
|
1 )  
2.0 x 10-6 M
|
|
2 )  
1.0 x 10-4 M
|
|
3 )  
1.6 x 10-4 M
|
|
4 )  
4.0 x 10-10 M
|
| see the answer see the solution |
|
94)
Benzene and toluene form nearly ideal solutions. At 20°C, thevapour pressure of benzene is 75 torr and
that of toluene is 22 torr. The partial vapour pressure of benzene at 20°C for a solution containing 78 g
of benzene and 46 g of toluene in torr is
|
|
|
1 )  
50
|
|
2 )  
25
|
|
3 )  
37.5
|
|
4 )  
53.5
|
| see the answer see the solution |
|
95)
The exothermic formation of ClF3 is represented by the equation :

Which of the following will increase the quantity of ClF3 in an equilibrium mixture of
Cl2, F2 and ClF3?
|
|
|
1 )  
Increasing the temperature
|
|
2 )  
Removing Cl2
|
|
3 )  
Increasing the volume of the container
|
|
4 )  
Adding F2
|
| see the answer see the solution |
|
96)
Two solutions of a substance (non electrolyte) are mixed in the following manner. 480 ml of 1.5 M first
solution + 520 mL of 1.2 M second solution. What is the molarity of the final mixture ?
|
|
|
1 )  
1.20 M
|
|
2 )  
1.50 M
|
|
3 )  
1.344 M
|
|
4 )  
2.70 M
|
| see the answer see the solution |
|
97)
For the reaction

(Kc = 1.8 x 10-6 at 184°C)
(R = 0.0831 kJ / (mol.K))
When Kp and Kc are compared at 184°C it is found that
|
|
|
1 )  
Kp is greater than Kc
|
|
2 )  
Kp is less than Kc
|
|
3 )  
Kp = Kc
|
|
4 )  
Whether Kp is greater than,
less than or equal to Kc depends upon the total gas pressure
|
| see the answer see the solution |
|
98)
Hydrogen ion concentration in mol/L in a solution of pH = 5.4 will be :
|
|
|
1 )  
3.98 x 108
|
|
2 )  
3.88 x 106
|
|
3 )  
3.68 x 10-6
|
|
4 )  
3.98 x 10-6
|
| see the answer see the solution |
|
99)
A reacion involving two different reactants can never be
|
|
|
1 )  
unimolecular reaction
|
|
2 )  
first order reaction
|
|
3 )  
second order reaction
|
|
4 )  
bimolecular reaction
|
| see the answer see the solution |
|
100)
If we consider that 1/6, in place of 1/12, mass of carbon atom is taken to be the relative atomic mass
unit, the mass of one mole of substance will
|
|
|
1 )  
decrease twice
|
|
2 )  
increase two fold
|
|
3 )  
remain unchanged
|
|
4 )  
be a function of the molecular mass of the substance
|
| see the answer see the solution |
|
101)
In a multi-electron atom, which of the following orbitals described by the three quantum number will
will have the same energy in the absence of magnetic and elctric fields ?
(a) n = 1, l = 0, m = 0
(b) n = 2, l = 0, m = 0
(c) n = 2, l = 1, m = 1
(d) n = 3, l = 2, m = 0
(e) n = 3, l = 2, m = 0
|
|
|
1 )  
(a) and (b)
|
|
2 )  
(b) and (c)
|
|
3 )  
(c) and (d)
|
|
4 )  
(d) and (e)
|
| see the answer see the solution |
|
102)
During the process of electrolytic refining of copper, some metals present as impurity settle as "anode
mud". These are
|
|
|
1 )  
Sn and Ag
|
|
2 )  
Pb and Zn
|
|
3 )  
Ag and Au
|
|
4 )  
Fe and Ni
|
| see the answer see the solution |
|
103)
|
Electrolyte
|
KCl
|
KNO3
|
HCl
|
NaOAc
|
NaCl
|
|
A∞(S cm2 mol-1)
|
149.9
|
145.0
|
426.2
|
91.0
|
126.5
|
Calculate Δ∞HOAc using appropriate molar
conductances of the electrolytes listed above at infinite dilution in H2O at 25°C
|
|
|
1 )  
517.2
|
|
2 )  
552.7
|
|
3 )  
390.7
|
|
4 )  
217.5
|
| see the answer see the solution |
|
104)
A schematic plot of lnK eq versus inverse of temperature for a reaction is shown below

The reaction must be
|
|
|
1 )  
exothermic
|
|
2 )  
endothermic
|
|
3 )  
one with negligible enthalpy change
|
|
4 )  
highly spontaneous at ordinary temperature
|
| see the answer see the solution |
|
105)
The disperse phase in colloidal iron (III) hydroxide and colloidal gold is positively and negatively charged,
respectively. Which of the following statements is NOT correct?
|
|
|
1 )  
Magnesium chloride solution coagulates, the gold sol more readily than the iron (III) hydroxide sol.
|
|
2 )  
Sodium sulphate solution causes coagulation in both sols
|
|
3 )  
Mixing the sols has no effect
|
|
4 )  
Coagulation in both sols can be brought about by electrophoresis
|
| see the answer see the solution |
|
106)
Based on lattice energy and other considerations which one of the following alkali metal chlorides is
expected to have the highest melting point ?
|
|
|
1 )  
LiCl
|
|
2 )  
NaCl
|
|
3 )  
KCl
|
|
4 )  
RbCl
|
| see the answer see the solution |
|
107)
Heating mixture of Cu2O and Cu2S will give
|
|
|
1 )  
Cu + SO2
|
|
2 )  
Cu + SO3
|
|
3 )  
CuO + CuS
|
|
4 )  
Cu2SO3
|
| see the answer see the solution |
|
108)
The molecular shapes of SF4, CF4 and XeF4 are
|
|
|
1 )  
the same with 2, 0 and 1 lone pairs of electrons
|
|
2 )  
the same with 1, 1 and 1 lone pair of electrons on the central atoms, respectively
|
|
3 )  
different with 0, 1 and 2 lone pairs of electrons on the central atom, respectively
|
|
4 )  
different with 1, 0 and 2 lone pairs of electrons on the central atom, respectively
|
| see the answer see the solution |
|
109)
The number and type of bonds between two carbon atoms in calcium carbide are
|
|
|
1 )  
One sigma, one pi
|
|
2 )  
One sigma, two pi
|
|
3 )  
Two sigma, one pi
|
|
4 )  
Two sigma, two pi
|
| see the answer see the solution |
|
110)
The oxidation state of chromium in the final product formed by the reaction between Kl and acidified
potassium dichromate solution is
|
|
|
1 )  
+4
|
|
2 )  
+6
|
|
3 )  
+2
|
|
4 )  
+3
|
| see the answer see the solution |
|
111)
The number of hydrogen atom(s) attached to phosphorus atom in hypophosphorous acid is
|
|
|
1 )  
zero
|
|
2 )  
two
|
|
3 )  
one
|
|
4 )  
three
|
| see the answer see the solution |
|
112)
What is the conjugate base of OH- ?
|
|
|
1 )  
O2
|
|
2 )  
H2O
|
|
3 )  
O-
|
|
4 )  
O2-
|
| see the answer see the solution |
|
113)
The correct order of the thermal stability of hydrogen halides (H-X) is
|
|
|
1 )  
HI > HBr > HCl > HF
|
|
2 )  
HF > HCl > HBr > HI
|
|
3 )  
HCl < HF > HBr < HI
|
|
4 )  
HI > HCl < HF > HBr
|
| see the answer see the solution |
|
114)
Heating an aqueous solution of aluminium chloride to dryness will give
|
|
|
1 )  
AlCl3
|
|
2 )  
Al2Cl6
|
|
3 )  
Al2O3
|
|
4 )  
Al(OH)Cl2
|
| see the answer see the solution |
|
115)
Calomel (Hg2Cl2) on reaction with ammonium hydroxide gives
|
|
|
1 )  
HgNH2Cl
|
|
2 )  
NH2-Hg-Hg-Cl
|
|
3 )  
Hg2O
|
|
4 )  
HgO
|
| see the answer see the solution |
|
116)
In which of the following arrangeements the order is NOT according to
the property indicated against it ?
|
|
1 )  
Al3+ < Mg2+ < Na+ < F- :
Increaing ionic size
|
2 )  
B < C < N < O :
Increasing first ionization enthalpy
|
3 )  
I < Br < F < Cl :
Increasing electron gain enthalpy (with negative sign)
|
4 )  
Li < Na < K < Rb :
Increasing metallic radius
|
| see the answer see the solution |
|
117)
In silicon dioxide
|
|
|
1 )  
each silicon atom is surrounded by four oxygen atoms and each
oxygen atom is bonded to two silicon atoms
|
|
2 )  
each silicon atom is surrounded by two oxygen atoms and each oxygen atom is bonded to two
silicon atoms
|
|
3 )  
silicon atom is bonded to two oxygen atoms
|
|
4 )  
there are double bonds between silicon and oxygen atoms
|
| see the answer see the solution |
|
118)
Of the following sets which one does NOT contain isoelectronic species ?
|
|
|
1 )  
PO43- , SO42- , Cl4-
|
|
2 )  
CN-, N2, C22-
|
|
3 )  
BO33- , CO33- , NO3-
|
|
4 )  
SO32- , CO32- , NO3-
|
| see the answer see the solution |
|
119)
The lanthanide contration is responsible for the fact that
|
|
|
1 )  
Zr and Y have about the same radius
|
|
2 )  
Zr and Nb have similar oxidation state
|
|
3 )  
Zr and Hf have about the same radius
|
|
4 )  
Zr and Zn have the same oxidation state
|
| see the answer see the solution |
|
120)
The IUPAC name of the coordination compound K3[Fe(CN)6] is
|
|
|
2 )  
Potassium hexacyanoferrate (II)
1
|
|
3 )  
Potassium hexacyanoiron (II)
|
|
4 )  
Tripotassium hexacyanoiron (II)
|
| see the answer see the solution |
|
121)
Which of the following compounds shows optical isomerism ?
|
|
|
2 )  
[Cu(NH3)2]2+
1
4]2-
|
|
3 )  
[Cr(C24O4)3]3-
|
|
4 )  
[Co(CN)6]3-
|
| see the answer see the solution |
|
122)
Which one of the following cyano complexes would exhibit the lowest value of paramagnetic behaviour?
(At. Nos : Cr = 24, Mn = 25, Fe = 26, Co = 27)
|
|
|
2 )  
[Cr(CN)6]3-
1
6]3-
|
|
3 )  
[Fe(CN)6]3-
|
|
4 )  
[Co(CN)6]3-
|
| see the answer see the solution |
|
123)
2-Methylbutane on reacting with bromine in the presence of sunlight gives mainly
|
|
|
1 )  
1-bromo-2-methylbutane
|
|
2 )  
2-bromo-2-methylbutane
|
|
3 )  
2-bromo-3-methylbutane
|
|
4 )  
1-bromo-3-methylbutane
|
| see the answer see the solution |
|
124)
A photon of hard gamma radiation knocks a proton out of
1224Mg nucleus to form
|
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1 )  
the isotope of parent nucleus
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2 )  
the isobear of parent nucleus
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3 )  
the nuclide 1123 Na
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4 )  
the isobar of 1123 Na
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| see the answer see the solution |
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125)
The best reagent to convert pent-3-en-2-ol into pent-3-en-2-one is
|
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|
1 )  
Acidic permanganate
|
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2 )  
Acidic dichromate
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3 )  
Chromic anhydride in glacial acetic acid
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4 )  
Pyridinium chloro-chromate
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| see the answer see the solution |
|
126)
Tertiary alkyl halides are practically inert to substitution by SN2 mechanism because of
|
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|
1 )  
insolubility
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2 )  
instability
|
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3 )  
inductive effect
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4 )  
steric hindrace
|
| see the answer see the solution |
|
127)
In both DNA and RNA, heterocylic base and phosphate ester linkages are at
|
|
|
1 )  
C'5 and C'2 respectively of the sugar molecule
|
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2 )  
C'2 and C'5 respectively of the sugar molecule
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3 )  
C'1 and C'5 respectively of the sugar molecule
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4 )  
C'5 and C'1 respectively of the sugar molecule
|
| see the answer see the solution |
|
128)
Reaction of one molecule of HBr with one molecule of 1, 3-butadiene at 40°C gives predominantly
|
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|
1 )  
3-bromobutene under kinetically controlled conditions
|
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2 )  
1-bromo-2-butene under thermodynamically controlled conditions
|
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3 )  
3-bromobutene under thermodynamically controlled conditions
|
|
4 )  
1-bromo-2-butene under kinetically controlled conditions
|
| see the answer see the solution |
|
129)
Among the following acids which has the lowest pKa value ?
|
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|
1 )  
CH3COOH
|
|
2 )  
HCOOH
|
|
3 )  
(CH3)2CH - COOH
|
|
4 )  
CH3CH2COOH
|
| see the answer see the solution |
|
130)
The decreasing order of nucleophilicity among the nucleophiles

|
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|
1 )  
(a), (b), (c), (d)
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2 )  
(d), (c), (b), (a)
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3 )  
(b), (c), (a), (d)
|
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4 )  
(c), (b), (a), (d)
|
| see the answer see the solution |
|
131)
Which one of the following methods is neither meant for the synthesis nor for separation of amines ?
|
|
|
1 )  
Hinsberg method
|
|
2 )  
Hofmann method
|
|
3 )  
Wurtz reaction
|
|
4 )  
Curtius reaction
|
| see the answer see the solution |
|
132)
Which of the following is fully fluorinated polymer ?
|
|
|
1 )  
Neoprene
|
|
2 )  
Teflon
|
|
3 )  
Thiokol
|
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4 )  
PVC
|
| see the answer see the solution |
|
133)
Of the five isomeric hexanes, the isomer which can give two monochlorinated compounds is
|
|
|
1 )  
n-hexane
|
|
2 )  
2, 3-dimethylbutane
|
|
3 )  
2, 2-dimethylbutane
|
|
4 )  
2-methylpentane
|
| see the answer see the solution |
|
134)
Alkyl halides react with dialkyl copper reagents to give
|
|
|
1 )  
alkenes
|
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2 )  
alkyl copper halides
|
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3 )  
alkanes
|
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4 )  
alkenyl halides
|
| see the answer see the solution |
|
135)
Acid catalyzed hydration of alkenes except ethene leads to the formation of
|
|
|
1 )  
primary alcohol
|
|
2 )  
secondary or tertiary alcohol
|
|
3 )  
mixture of primary and secondary alcohols
|
|
4 )  
mixture of secondary and tertiary alcohols
|
| see the answer see the solution |
|
136)
Amongest the following the most basic compound is
|
|
|
1 )  
benzylamine
|
|
2 )  
aniline
|
|
3 )  
acetanilide
|
|
4 )  
p-nitroaniline
|
| see the answer see the solution |
|
137)
Which types of isomerism is shown by 2, 3-dichlorobutane ?
|
|
|
1 )  
Diastereo
|
|
2 )  
Optical
|
|
3 )  
Geometric
|
|
4 )  
Sturctural
|
| see the answer see the solution |
|
138)
The reaction

is fastest when X is
|
|
|
1 )  
Cl
|
|
2 )  
NH2
|
|
3 )  
OC2H5
|
|
4 )  
OCOR
|
| see the answer see the solution |
|
139)
Elimination of bromine from 2-bromobutane results in the formaiton of
|
|
|
1 )  
equimolar mixture of 1 and 2-butene
|
|
2 )  
predominantly 2-butene
|
|
3 )  
prdominantly 1-butene
|
|
4 )  
predominantly 2-butyne
|
| see the answer see the solution |
|
140)
Equimolar solutions in the same solvent have
|
|
|
1 )  
Same boiling point but different freezing point
|
|
2 )  
Same freezing point but different boiling point
|
|
3 )  
Same boiling and same freezing points
|
|
4 )  
Different boiling and different freezing points
|
| see the answer see the solution |
|
141)
Which of the following statements in relation to the hydrogen atom is correct ?
|
|
|
1 )  
3s orbital is lower in energy than 3p orbital
|
|
2 )  
3p orbital is lower in energy than 3d orbital
|
|
3 )  
3s and 3p orbitals are of lower energy than 3d orbital
|
|
4 )  
3s, 3p and 3d orbitals all have the same energy
|
| see the answer see the solution |
|
142)
The structure of diborane (B2H6) contains
|
|
|
1 )  
four 2c-2e bonds and two 3c-2e bonds
|
|
2 )  
two 2c-2e bonds and four 3c-2e bonds
|
|
3 )  
two 2c-2e bonds and two 3c-3e bonds
|
|
4 )  
four 2c-2e bonds and four 3c-2e bonds
|
| see the answer see the solution |
|
143)
The value of the 'spin only' magnetic moment for one of the following configurations is 2.84 BM. The
correct one is
|
|
|
1 )  
d4 (in strong ligand field)
|
|
2 )  
d4 (in weak ligand field)
|
|
3 )  
d3 (in weak as well as in strong fields)
|
|
4 )  
d5 (in strong ligand field)
|
| see the answer see the solution |
|
144)
Which of the following factors may be regarded as the main cause of lanthanide contraction ?
|
|
|
1 )  
Poor shielding of one of 4f electron by another in the subshell
|
|
2 )  
Effective shielding of one of 4f electrons by another in the subshell
|
|
3 )  
Poorer shielding of 5d electrons by 4f electrons
|
|
4 )  
Greater shielding of 5d electron by 4f electrons
|
| see the answer see the solution |
|
145)
Reaction of cyclohexanone with dimethylamine in the presence of catalytic amount of an acid forms a
compound if water during the reaction is continuously removed. The compound formed is generally
known as
|
|
|
1 )  
a Schiff's base
|
|
2 )  
an enamine
|
|
3 )  
an imine
|
|
4 )  
an amine
|
| see the answer see the solution |
|
146)
p-cresol reacts with chloroform in alkaline medium to give the compound A which adds hydrogen
cyanide to form, the compound B. The latter on acidic hydrolysis gives chiral carboxylic acid. The
structure of the carboxylic acid is
|
|
1 )  
|
2 )  
|
3 )  
|
4 )  
|
| see the answer see the solution |
|
147)
An organic compound having molecular mass 60 is found to contain C = 20%, H = 6.67% heating it
gives NH3 alongwith a solid residue. the solid residue give violet colour with alkaline copper sulphate
solution. The compound is
|
|
|
1 )  
CH3NCO
|
|
2 )  
CH3CONH2
|
|
3 )  
(NH2)2CO
|
|
4 )  
CH3CH2CONH2
|
| see the answer see the solution |
|
148)
If the bond dissociation energies of XY, X2 and Y2 (all diatomic molecules)
are in the ratio of 1 : 1 : 0.5
and ΔfH for the formation of XY is -200 kJ mole-1.
The bond dissociation energy of X2 will be
|
|
|
1 )  
100 kJ mol-1
|
|
2 )  
200 kJ mol-1
|
|
3 )  
300 kJ mol-1
|
|
4 )  
400 kJ mol-1
|
| see the answer see the solution |
|
149)
t1/4 can be taken as the time taken for the concentration of a reactant to drop to
3/4 of its initial value. If the rate constant for a first order reaction is K, the
t1/4 can be written as
|
|
|
1 )  
0.10 / K
|
|
2 )  
0.29 / K
|
|
3 )  
0.69 / K
|
|
4 )  
0.75 / K
|
| see the answer see the solution |
|
150)
An amount of solid NH4HS is placed in a flask already containing ammonia gas at a certain temperature
and 0.50 atm. pressure. Ammonium hydrogen sulphide decoomposes to yield NH3 and H2S gases
in the flask. When the decomposition reaction reaches equilibrium, the total pressure in the flask rises
to 0.84 atm. The equilibrium constant for NH3HS decomposition at this temperature is
|
|
|
1 )  
0.30
|
|
2 )  
0.18
|
|
3 )  
0.17
|
|
4 )  
0.11
|
| see the answer see the solution |